dc.contributor.author | Günsel, Armağan | |
dc.contributor.author | Mutlu, Nazire | |
dc.contributor.author | Yaşa Atmaca, Göknur | |
dc.contributor.author | Günsel, Hilal | |
dc.contributor.author | Bilgiçli, Ahmet T. | |
dc.contributor.author | Erdoğmuş, Ali | |
dc.contributor.author | Nilüfer Yarasir, M. | |
dc.date.accessioned | 2023-07-18T07:12:50Z | |
dc.date.available | 2023-07-18T07:12:50Z | |
dc.date.issued | 2023 | en_US |
dc.identifier.citation | Günsel, A., Mutlu, N., Yaşa Atmaca, G., Günsel, H., Bilgiçli, A. T., Erdoğmuş, A., & Nilüfer Yarasir, M. (2023). Novel graphene Oxide/Zinc phthalocyanine composites bearing 3-chloro-4-fluorophen potential usage for Sono/Photochemical applications. ChemistrySelect, 8(12) doi:10.1002/slct.202204546 | en_US |
dc.identifier.uri | https://hdl.handle.net/20.500.14002/2006 | |
dc.description.abstract | The aim of this paper is to explore the therapeutic contribution of graphene oxide (GO) to new sono/photosensitizers through sono/photochemical studies for the first time. For this purpose, new zinc (II) phthalocyanine bearing 3-chloro-4-fluorophenoxy 2 was synthesized and then its GO-based composites were prepared by non-covalently coating ZnPc 2 on the graphene oxide surface. The photoactivity of these materials was compared and discussed in terms of their potential ability to be used in photosensitizer in photodynamic therapy (PDT) and sono-photodynamic therapy (SPDT). In these application areas, GO can serve as photosensitizer carrier, while ZnPc 2 can be acting as PDT/SPDT agent. Therefore, phthalocyanine composites containing different percentages of graphene oxide by weight (wt.% GO) were prepared. SEM (scanning electron microscopy) results supported the interaction between GO and ZnPc 2. In the sono-photochemical study, both ZnPc 2 and its composites gave very higher ΦΔ values than the photochemical study. The sono-photochemical ΦΔ values were found to be 0.928 for 0 wt.% GO, 0.869 for 0.25 wt.% GO, 0.891 for 0.50 wt.% GO, 0.868 for 1 wt.% GO, 0.908 for 3 wt.% GO, 0.845 for 5 wt.% GO and 0.851 for 10 wt.% GO, respectively. According to obtained results, these materials could be promise as good photosensitizers for both the photochemical study and the sono-photochemical study due to their very high singlet oxygen generation. © 2023 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. | en_US |
dc.language.iso | eng | en_US |
dc.publisher | John Wiley and Sons Inc | en_US |
dc.relation.ispartof | ChemistrySelect | en_US |
dc.rights | info:eu-repo/semantics/openAccess | en_US |
dc.title | Novel Graphene Oxide/Zinc Phthalocyanine Composites Bearing 3-Chloro-4-Fluorophen Potential Usage for Sono/Photochemical Applications | en_US |
dc.type | article | en_US |
dc.authorid | 0000-0002-4343-6539 | en_US |
dc.department | Fakülteler, Teknoloji Fakültesi, Mühendislik Temel Bilimleri Bölümü | en_US |
dc.institutionauthor | Günsel, Hilal | |
dc.identifier.doi | 10.1002/slct.202204546 | en_US |
dc.identifier.volume | 8 | en_US |
dc.identifier.issue | 12 | en_US |
dc.relation.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | en_US |
dc.authorscopusid | 57934860700 | en_US |
dc.identifier.wosquality | Q3 | en_US |
dc.identifier.scopus | 2-s2.0-85151563477 | en_US |